Rift valleys are large depressions formed by tectonic stretching forces. Volcanoes often occur in rift valleys, within the rift itself or on the rift flanks as e.g. in East Africa. The magma responsible for this volcanism is formed in the upper mantle and ponds at the boundary between crust and mantle. For many years, the question of why volcanoes develop outside the rift zone in an apparently unexpected location offset by tens of kilometers from the source of molten magma directly beneath the rift has remained unanswered. Scientists have now shown that the pattern of stresses in the crust changes when the crust thins due to stretching and becomes gravitationally unloaded. As a consequence of this stress pattern, the path of the magma pockets ascending from the ponding zone is deviated diagonally to the sides of the rift. Eventually, the magma pockets emerge at distances of tens, sometime hundreds of kilometers from the rift axis, creating the so-called off-rift volcanoes.

Source: Off-rift volcanoes explained